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MENTAL MODEL · M5297

Gibbs Free Energy

Gibbs Free Energy
SystemsHigh supportSystems Theory
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Version 1.0.0 · Updated 2026-07-30

CORE DEFINITION

Under constant temperature and pressure, the energy available in a system to do useful work. Whether a process can occur spontaneously depends on the change in Gibbs free energy (ΔG). If ΔG < 0, the process is spontaneous; if ΔG > 0, energy input is required.

SCAFFOLDING EFFECT

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An energy criterion for judging whether something can be accomplished. When driving change, calculate the system's ΔG (benefit minus entropy increase). If the result is negative, the change will proceed smoothly; if positive, you must continuously input significant external energy (strong will/funding) to maintain it, otherwise it will revert as soon as you let go.

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ΔG = ΔH - TΔS, i.e., free energy change = enthalpy change (energy) minus temperature times entropy change (disorder cost). Systems spontaneously tend toward lower free energy states; if the target state has higher free energy, continuous energy input is required to maintain it, and it will revert once energy is removed. Applied to organizational/personal change: the 'spontaneity' of change depends on whether it reduces the system's total resistance (benefit minus friction); otherwise, it must be sustained by external will.

MINIMUM ACTION

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Source support: Explicit

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    en.wikipedia.orghttps://en.wikipedia.org/wiki/Gibbs_free_energyZH · Explicit
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