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MENTAL MODEL · M0085

Second Law of Thermodynamics

Second Law of Thermodynamics
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Version 1.0.0 · Updated 2026-07-28

CORE DEFINITION

One entropy formulation of the second law says that the total entropy of a macroscopic isolated system does not decrease: it stays constant for a reversible process and increases for an irreversible one. An isolated system exchanges neither matter nor energy with its surroundings, so external work cannot be invoked as an exception. A local system can reduce its entropy through exchanges with its environment.

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Beyond energy conservation, checks the direction of thermal processes, heat-engine efficiency limits, and irreversible losses. Comparing organizational or household “disorder” to entropy is an analogy, not a physical proof of inevitable decline.

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Thermodynamic entropy is a state variable. Its change can be calculated using a reversible path between the same initial and final states; an actual irreversible process generates entropy for the system and surroundings together. Energy remains conserved, but not all energy can be converted into useful work over a cycle.

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    zh.wikipedia.orghttps://zh.wikipedia.org/wiki/%E7%83%AD%E5%8A%9B%E5%AD%A6%E7%AC%AC%E4%BA%8C%E5%AE%9A%E5%BE%8BZH · Explicit
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  • link
    openstax.orghttps://openstax.org/books/university-physics-volume-2/pages/4-6-entropyEN
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